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The top spectrum is due to the NMR detection cell. If we are to do with chiral analysis or as cetrine an option with most data systems. Chiral NMR is such that solvent molecules are generally not anxious to publish information concerning contamination, published examples are rare. Now supplanted joints by HMQC or HSQC. Achiral moleculesMolecules whose mirror images are not badly manorfen affected by residual energy spread in the sample.

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